Thermoset and thermoplastic process technologies for high-volume production of carbon-fiber-reinforced automotive parts

Logo (PresseBox) (Pfinztal, ) The project MAI Qfast within the MAI Carbon Cluster is carrying out a systematic evaluation of the potential of carbon-fiber-reinforced plastics (CFRPs) in combination with different manufacturing process technologies including design, manufacturing and benchmarking. Five different processes for CFRPs have been used to create structural components in automobiles. Both thermoset and thermoplastic matrix systems have been benchmarked and processed either by resin transfer molding (RTM) or compression molding. The project consortium consists of BASF as a material and semi-finished product supplier, the Fraunhofer Institute for Chemical Technology for material and process development and in particular the two independent OEMs Audi and BMW.

Thermoset or thermoplastic CFPRs?

Frequently asked questions about carbon fiber composites concern the selection of the matrix system, the most suitable processing technology and the resulting cycle time, ener-gy need, cost effectiveness, and static and dynamic performance of these components. The project MAI Qfast is compiling answers to these questions.

Ambitious floor panel structure as Demonstrator
As the main focus of MAI Qfast is a comparison of the specific potential of thermoset and thermoplastic CFRPs for large-scale production it was important that the chosen demon-strator - an ambitious floor panel structure - could be produced using either RTM or com-pression molding technology. Five different CFRP-materials and three different processes (RTM, SMC and LFT-D) have been developed for benchmarking, and for a demonstrator derived from a floor panel structure. The influence of the technology, the material and the component geometry on the cost and performance and the applicability in large-volume production is of major importance for OEMs and their suppliers. Only commercially-available materials have been used to ensure a complete comparability. During the whole project the engineering work was accompanied by simulation.

Compression molding or RTM?
The compression molding processes are represented by thermoset sheet molding com-pound (SMC) and direct long-fiber-reinforced thermoplastics (D-LFT), both combined with continuous fiber reinforcements to improve the mechanical properties. Beside the com-pression molding processes, the RTM process using a thermosetting epoxy, a thermoset-ting polyurethane and a thermoplastic polyamide as resin was selected. For the compara-bility of these processes one type of carbon fiber was chosen and used for each technology. Only slight modifications, such as the sizing of the fiber, were carried out.

Comparability of the Benchmark
The same type of carbon fiber (with adapted sizing) was used for all trials, either in ther-moplastic or thermosetting resin, as well as for the production of semi-finished sheets for sheet molding compound (SMC) processing. As a benchmark for the carbon fiber SMC, the long fiber thermoplastic direct process (LFT-D) based on carbon fibers was performed. The LFT-D process combines an in-line compounding unit with a subsequent compression molding unit. Fibers and resin are gravimetrically dosed and homogenized in the extruder. Meanwhile the unidirectional reinforcing tapes are heated up and brought into the shape of the demonstrator. The extruded D-LFT material is placed in the mold together with the carbon fiber structure and pressed to the final part. After demolding, post processing (for example trimming) is required, depending on the application.

For the third alternative, the RTM process, the carbon fibers were processed to form a non-crimp unidirectional fabric. In this process, several layers of the textile are stacked together, heated and formed to a stiff 3D-shape - a so-called preform. For comparability the stacking of the preforms is adopted for all RTM resin systems. The preform is then placed into the mold, the mold closes and the preform is infiltrated. After a certain curing time the part can be demolded.

Demonstrator production
The demonstrator parts for the RTM and the two compression molding processes differ in some details (e.g. ribs at the compression molded parts) according to the material involved, but fit in an identical design space. Before investments were made in mold hardware, the component design was analyzed and optimized using the mechanical properties of the selected CFRP systems, which were determined through the characterization of test specimens.

The demonstrator parts produced will now be tested, evaluated and validated in the next phase of the project.

This report is based on results achieved in the MAI Qfast (03Mai05) project of the MAI Car-bon Leading-Edge Cluster. This project is funded by the German Federal Ministry for Edu-cation and Research, and managed by the Project Executive Agency in Jülich.

About the Fraunhofer ICT and the Polymer Engineering Department
The Fraunhofer Institute for Chemical Technology ICT is one of the 67 institutes and re-search centers that currently make up the Fraunhofer-Gesellschaft. Beside contractual research for industry, the Fraunhofer ICT also works together with commercial enterprises in research projects co-funded by the German government and the European Union.

The Polymer Engineering Department is one of the leading application-related research institutions in polymer development. The Institute's employees, who mainly have an engi-neering background, work together with partners and customers on novel networked pro-cess steps, and continuously broaden the application fields of contemporary polymer ma-terials. The department offers research and development services from the initial idea to the manufacture of prototypes - all in one location.
Further information at: www.ict.fraunhofer.de

About MAI Carbon
The Leading-Edge Cluster Initiative MAI Carbon, which was founded at the suggestion of Carbon Composites e.V. (CCeV), is made up of more than 90 businesses, educational and research institutions as well as organizations from the Munich-Augsburg-Ingolstadt region. The founding partners of MAI Carbon are: Audi, BMW, Premium AEROTEC, AIRBUS Heli-copters (ex Eurocopter), Voith and SGL Group, as well as the IHK Schwaben, the depart-ment for carbon composites (LCC) of the TU Munich and CCeV itself. All partners are active in the technological field of fiber-reinforced composite materials, in particular in the area of carbon-fiber-reinforced plastic (CFRP). Emphasis is placed on the user areas automobile and aerospace as well as mechanical and plant engineering.

The main objective that MAI Carbon is pursuing is to make the substance carbon fit for serial production, and to turn the Munich-Augsburg-Ingolstadt region into a European competence center for CFRP lightweight construction that covers the entire value-added chain of CFRP technology. It also aims to help the partners assume a global leading position in the key technology CFRP. This could create up to 4,500 new jobs in the region.
Further information at: www.mai-carbon.de

Kontakt

Fraunhofer Institut für Chemische Technologie ICT
Joseph-von-Fraunhoferstraße 7
D-76327 Pfinztal
Michael Karcher
Fraunhofer Institute for Chemical Technology ICT, Polymer Engineering
High-performance composites
Dr. Stefan Tröster
Fraunhofer-Institut Chemische Technologie
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